Collins faces a charge of assault with a deadly weapon with intent to kill.
Police say 43-year-old Jeanine Collins, a teacher's assistant at Union Academy, went to her ex-husband's apartment and they had an argument.Details on booking are unavailable.
That's when police say she got to his gun, a 9mm handgun, and shot him in the head during a struggle.
Collins initially told police that Marvin Collins had shot himself.
Once he was treated and released from the hospital - and was able to talk - Marvin Collins told detectives that Jeanine Collin had shot him. Detectives were able to arrest Jeanine Collins without incident.
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